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|On Route 2, right next to the entrance to Diglett’s Cave behind a smashable rock.
Starting from the Pewter City Pokémon Center, head South.
Continue following the path South as you walk out of the city and enter Route 2.
You’ll see the entrance to Diglett’s Cave to your East, and a smashable rock next to it. Use Rock Smash on it.
Go North and you’ll find the Orbeetlite at the end of the path behind the rock.